Bis{2,4-dichloro-6-[3-(dimethylamino)propyliminomethyl]phenolato}copper(II)
نویسنده
چکیده
In the title complex, [Cu(C(12)H(15)Cl(2)N(2)O)(2)], the Cu(II) ion is coordinated by one N,O-bidentate and one N,N',O-tridentate Schiff base ligand, resulting in a distorted CuN(3)O(2) square-based pyramidal coordination for the metal ion, with the O atoms lying trans to each other in the basal plane.
منابع مشابه
Bis{μ-2,4-di-tert-butyl-6-[3-(1H-imidazol-1-yl)propyliminomethyl]phenolato}bis[acetatocopper(II)]
In the centrosymmetric title compound, [Cu(2)(C(21)H(30)N(3)O)(2)(C(2)H(3)O(2))(2)], each Cu atom has a distorted tetra-hedral coordination geometry defined by N and O atoms in a chelate ring, N of an imidazole ring, and an acetate O atom. The uncoordinated acetate O atom is disordered over two sites with occupancies 0.7:0.3.
متن کاملBis[2,4-dichloro-6-(ethyliminomethyl)phenolato-κ2 N,O]nickel(II)
In the title compound, [Ni(C(9)H(8)Cl(2)NO)(2)], the Ni(II) ion lies on an inversion centre and is coordinated in a slightly distorted square-planar geometry by an N and an O atom from two symmetry-related bidentate 2,4-dichloro-6-(ethyl-imino-meth-yl)phenolate ligands. In the crystal structure, there are short Cl⋯Cl distances of 3.506 (1) and 3.350 (1) Å.
متن کاملDi-μ-thiocyanato-bis({2,4-dichloro-6-[2-(diethylamino)ethyliminomethyl]phenolato}copper(II))
The title compound, [Cu(2)(NCS)(2)(C(13)H(17)Cl(2)N(2)O)(2)], was obtained by the reaction of 3,5-dichloro-salicylaldehyde, N,N-diethyl-ethane-1,2-diamine, sodium thio-cyanate, and copper(II) acetate in an ethanol solution. It crystallizes as a centrosymmetric dimer with a very long Cu⋯S axial bond [2.972 (3) Å]. The Cu atom is five-coordinated by the three donor atoms of the Schiff base ligand...
متن کاملBis{2-[3-(dimethylamino)propyliminomethyl]-6-methoxyphenolato-κ3 N,N′,O 1}nickel(II)
The centrosymmetric title complex, [Ni(C(13)H(19)N(2)O(2))(2)], is a mononuclear nickel(II) complex. The Ni(II) atom is coordinated by four N atoms and two O atoms of two deprotonated Schiff base ligands, forming a slightly distorted octa-hedral coordination configuration, in which the tertiary N atoms occupy the axial positions.
متن کاملcatena-Poly[copper(II)-bis(μ-2,4-dichloro-6-formylphenolato)-κ3 O,O′:Cl 4;κ3 Cl 4:O,O′]
In the title compound, [Cu(C(7)H(3)Cl(2)O(2))(2)](n), the Cu(II) atom lies on a centre of inversion and adopts a [4+2] coordination mode, with two long axial Cu-Cl coordinative bonds complementing four Cu-O bonds from two 2,4-dichloro-6-formyl-phenolate ligands in a distorted square plane. π-π stacking inter-actions are also formed between neighbouring aromatic rings, with a centroid-centroid s...
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